Data-Driven Gas Sensing Analysis of Titanium-Doped Cadmium Oxide Thin Films

Muna Ahmed Issa, Nazar Abdulmahdi Jabir, Athraa Naji Jameel, Muhaned Zaidi and Hassan Hadi Darwoysh

References:

1. D.G. Cahill and T.H. Allen, “Thermal conductivity of sputtered and evaporated SiO2 and TiO2 optical coatings,” Appl. Phys. Lett., vol. 65, p. 309, 1994, [Online]. Available: https://doi.org/10.1063/1.112355.
2. S. Ben Amor, G. Baud, J.P. Besse and M. Jacquet, “Structural and optical properties of sputtered titanium films,” Mater. Sci. Eng. B, vol. 47, pp. 110-118, 1997.
3. P.S. Shinde, H.P. Deshmukh, S.H. Mujawar,
4. A.I. Inamdar and P.S. Patil, “Spray deposited titanium oxide thin films as passive counter electrodes,” Electrochim. Acta, vol. 52, pp. 3114-3120, 2007.
5. B. O’Regan and M. Grätzel, “A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films,” Nature, vol. 353, pp. 737-740, 1991, [Online]. Available: https://doi.org/10.1038/353737a0.
6. K.S. Kim and M.A. Barteau, “Structure and composition requirements for deoxygenation, dehydration, and ketonization reactions of carboxylic acids on TiO2 (001) single crystal surfaces,” J. Catal., vol. 125, pp. 353-375, 1990.
7. P. Babelon, A.S. Dequiedt, H. Mostesa-Sba,
8. S. Bourgeois, P. Sibillot and M. Sacilotti, “SEM and XPS studies of titanium dioxide thin films grown by MOCVD,” Thin Solid Films, vol. 322, pp. 63-67, 1998.
9. R.W. Matthews, “Photooxidation of organic impurities in water using thin films of titanium dioxide,” J. Phys. Chem., vol. 91, pp. 3328-3333, 1987, [Online]. Available: https://doi.org/10.1021/j100296a044.
10. A. Fujishima, T.N. Rao and D.A. Tryk, “Titanium dioxide photocatalysis,” J. Photochem. Photobiol. C, vol. 1, pp. 1-21, 2000.
11. B.M. Henry, “Method of depositing titanium dioxide (rutile) as a gate dielectric for MIS device fabrication,” US Patent 4,200,474, 1978.
12. M.R. Kozlowski, P.S. Tyler, W.H. Smyrl and
13. R.T. Atanasoski, “Anodic TiO2 thin films: photoelectrochemical, electrochemical, and structural study of heat-treated and RuO2-modified films,” J. Electrochem. Soc., vol. 136, pp. 442-450, 1989.
14. J.Y. Kim, D.W. Kim, H.S. Jung and K.S. Hong, “Influence of anatase-rutile phase transformation on dielectric properties of sol-gel derived TiO2 thin films,” Jpn. J. Appl. Phys., vol. 44, pp. 6148-6151, 2005.
15. C. Yang, H. Fan, Y. Xi, J. Chen and Z. Li, “Effects of depositing temperatures on structure and optical properties of TiO2 film deposited by ion beam assisted electron beam evaporation,” Appl. Surf. Sci., vol. 254, pp. 2685-2689, 2008.
16. V.G. Besserguenev, R.J.F. Pereira, M.C. Mateus,
17. I.V. Khmelinskii, R.C. Nicula and E. Burkel, “TiO2 thin film synthesis from complex precursors by CVD, its physical and photocatalytic properties,” Int. J. Photoenergy, vol. 5, pp. 99-105, 2003.
18. M.A. Issa and K.A. Aadim, “Optical and structural characterization of ZnO:NiO nanocomposite prepared by pulsed laser deposition method,” J. Opt., vol. 54, pp. 2357-2362, 2025.
19. H.P. Deshmukh, P.S. Shinde and P.S. Patil, “Structural, optical and electrical characterization of spray-deposited TiO2 thin films,” Mater. Sci. Eng. B, vol. 130, pp. 220-227, 2006.
20. M.A. Issa and K.A. Aadim, “Study the structural and optical properties of zinc oxide prepared by pulse laser deposition,” J. Opt., 2024.
21. M.A. Issa and K.A. Aadim, “Influence of laser energy on structural and optical properties of ZnO(x):NiO(1-x) films prepared by pulse laser deposition,” J. Opt., 2024.
22. W. Yang and C.A. Wolden, “Plasma-enhanced chemical vapor deposition of TiO2 thin films for dielectric applications,” Thin Solid Films, vol. 515, pp. 1708-1713, 2006.
23. O. Banakh, P.E. Schmid, R. Sanjines and F. Levy, “Electrical and optical properties of TiOx thin films deposited by reactive magnetron sputtering,” Surf. Coat. Technol., vol. 151-152, pp. 272-275, 2002.
24. P.B. Nair, V.B. Justinvictor, G.P. Daniel, K. Joy and P.V. Thomas, “Influence of film thickness and annealing atmosphere on the structural, optical and luminescence properties of nanocrystalline TiO2 thin films prepared by RF magnetron sputtering,” J. Mater. Sci.: Mater. Electron., vol. 24, pp. 2453-2460, 2013.
25. M.M. Momenin and Y. Ghayeb, “Preparation of cobalt coated TiO2 and WO3-TiO2 nanotube films via photo-assisted deposition with enhanced photocatalytic activity under visible light illumination,” Ceram. Int., vol. 42, pp. 7014-7022, 2016.
26. J. Xu, S. Shi, L. Li, X. Zhang, Y. Wang, X. Chen,
27. J. Wang, L. Lv, F. Zhang and W. Zhong, “Structural, optical, and ferromagnetic properties of Co-doped TiO2 films annealed in vacuum,” J. Appl. Phys., vol. 107, p. 053910, 2010.
28. R.R. Ahmed, T.H. Mubarak and I.H. Mohamed, “A study of structural and chemical properties of Ni1-xZnxFe2O4 ferrite powder prepared by co-precipitation method,” Digest J. Nanomater. Biostruct., vol. 17, pp. 741-748, 2022.
29. B.A. Bader, S.K. Muhammad, A.M. Jabbar,
30. K.H. Abass, S.S. Chiad and N.F. Habubi, “Synthesis and characterization of indium-doped CdO nanostructured thin films: a study on optical, morphological, and structural properties,” J. Nanostruct., vol. 10, pp. 744-750, 2020.
31. N. Venkatachalam, M. Palanichamy, B. Arabindoo and V. Murugesan, “Enhanced photocatalytic degradation of 4-chlorophenol by Zr4+ doped nano TiO2,” J. Mol. Catal. A Chem., vol. 266, pp. 158-165, 2007.
32. K. Bouabid, A. Ihlal, Y. Amir, A. Sdaq, A. Assabbane, Y. Ait-Ichou, A. Outzourhit, E.L. Ameziane and
33. G. Nouet, “Optical study of TiO2 thin films prepared by sol-gel,” Ferroelectrics, vol. 372, pp. 69-75, 2008.
34. R.S. Ali, N.A.H. Al Aaraji, E.H. Hadi, K.H. Abass, N.F. Habubi and S.S. Chiad, “Effect of lithium on structural and optical properties of nanostructured CuS thin films,” J. Nanostruct., vol. 10, pp. 810-816, 2020.
35. M. Hamadanian, A. Reisi-Vanani and A. Majedi, “Sol-gel preparation and characterization of Co/TiO2 nanoparticles: application to the degradation of methyl orange,” J. Iran. Chem. Soc., vol. 7, pp. 52-58, 2010.
36. H. Pulker, G. Paesold and E. Ritter, “Refractive indices of TiO2 films produced by reactive evaporation of various titanium-oxygen phases,” Appl. Opt., vol. 15, pp. 2986-2991, 1976.
37. H.Y. Ha, S.W. Nam, T.H. Lim, I.H. Oh and
38. S.A. Hong, “Properties of the TiO2 membranes prepared by CVD of titanium tetraisopropoxide,” J. Membr. Sci., vol. 111, pp. 81-92, 1996.
39. H.S. Al-Rikabi, M.H. Al-Timimi and W.H. Albanda, “Morphological and optical properties of MgO1-xZnSx thin films,” Digest J. Nanomater. Biostruct., vol. 17, pp. 889-897, 2022.
40. A.J. Ghazai, O.M. Abdulmunem, K.Y. Qader,
41. S.S. Chiad and N.F. Habubi, “Investigation of some physical properties of Mn doped ZnS nano thin films,” AIP Conf. Proc., vol. 2213, p. 020101, 2020.
42. P.J.L. Herve and L.K.J. Vandamme, “General relation between refractive index and energy gap in semiconductors,” Infrared Phys. Technol., vol. 35, pp. 609-615, 1994.
43. S. Douven, J.G. Mahy, C. Wolfs, C. Reyserhove,
44. D. Poelman, F. Devred, E.M. Gaigneaux and
45. S.D. Lambert, “Efficient N, Fe co-doped TiO2 active under cost-effective visible LED light: from powders to films,” Catalysts, vol. 10, p. 547, 2020.
46. S. Bhat, K.M. Sandeep, P. Kumar,
47. S.M. Dharmaprakash and K. Byrappa, “Characterization of transparent semiconducting cobalt doped titanium dioxide thin films prepared by sol-gel process,” J. Mater. Sci.: Mater. Electron., vol. 29, pp. 1098-1106, 2018.
48. V.C. Ferreira, M.R. Nunes, A.J. Silvestre and
49. O.C. Monteiro, “Synthesis and properties of Co-doped titanate nanotubes and their optical sensitization with methylene blue,” Mater. Chem. Phys., vol. 142, pp. 355-362, 2013.
50. S.S. Chiad, N.F. Habubi, W.H. Abass and
51. M.H. Abdul-Allah, “Effect of thickness on the optical and dispersion parameters of Cd0.4Se0.6 thin films,” J. Optoelectron. Adv. Mater., vol. 18, pp. 822-826, 2016.
52. M.M. Khalaf, H.M.A. El-Lateef and H.M. Ali, “Optical and photocatalytic measurements of Co-TiO2 nanoparticle thin films,” Plasmonics, vol. 13, pp. 1795-1802, 2018.
53. J. Tian, H. Deng, L. Sun, H. Kong, P. Yang and J. Chu, “Effects of Co doping on structure and optical properties of TiO2 thin films prepared by sol-gel method,” Thin Solid Films, vol. 520, pp. 5179-5183, 2012.
54. C. Rath, P. Mohanty, V. Pandey and C. Mishra, “Oxygen vacancy induced structural phase transformation in TiO2 nanoparticles,” J. Phys. D, vol. 42, p. 205101, 2009.
55. Z. Tan, K. Sato and S. Ohara, “Synthesis of layered nanostructured TiO2 by hydrothermal method,” Adv. Powder Technol., vol. 26, pp. 296-302, 2015.
56. A. Ghazai, K. Qader, N.F. Habubi, S.S. Chiad and
57. O. Abdulmunem, “Structural and optical performance of the doped ZnO nano-thin films by CSP,” IOP Conf. Ser.: Mater. Sci. Eng., vol. 870, p. 012048, 2020.
58. A. Boutlala, F. Bourfaa, M. Mahtili and
59. A. Bouaballou, “Deposition of Co-doped TiO2 thin films by sol-gel method,” IOP Conf. Ser.: Mater. Sci. Eng., vol. 108, p. 012048, 2016.
60. A. Chanda, S.R. Joshi, V.R. Akshay, S. Varma,
61. J. Singh, M. Vasundhara and P. Shukla, “Structural and optical properties of multilayered undoped and cobalt doped TiO2 thin films,” Appl. Surf. Sci., vol. 536, p. 147830, 2021.
62. J.C. González-Torres, L.A. Cipriano, E. Poulain,
63. V. Domínguez-Soria, R. García-Cruz and O. Olvera-Neria, “Optical properties of anatase TiO2: synergy between transition metal doping and oxygen vacancies,” J. Mol. Model., vol. 24, pp. 1-11, 2018.
64. S. Ghasemi, S. Rahimnejad, S.S. Rahman, S. Rohani and M.R. Gholami, “Transition metal ions effect on the properties and photocatalytic activity of nanocrystalline TiO2 prepared in an ionic liquid,” J. Hazard. Mater., vol. 172, pp. 1573-1578, 2009.
65. O.A. El-Gammal, A.E. Alsayed Fouda and
66. D. Mohamed Nabih, “Synthesis, spectral characterization, DFT and in vitro antibacterial activity of Zn(II), Cd(II) and Hg(II) complexes derived from a new thiosemicarbazid,” Lett. Appl. NanoBioScience, vol. 8, pp. 715-722, 2019.
67. F. Mostaghni and Y. Abed, “Structural determination of Co/TiO2 nanocomposite: XRD technique and simulation analysis,” Mater. Sci.-Poland, vol. 34, pp. 534-539, 2016.
68. E.H. Hadi, M.A. Abbsa, A.A. Khadayeir, Z.M. Abood, N.F. Habubi and S.S. Chiad, “Effects of Mn doping on the characterization of nanostructured TiO2 thin films deposited via chemical spray pyrolysis method,” J. Phys.: Conf. Ser., vol. 1664, p. 012094, 2020.
69. A.A. Kamil, N.A. Bakr, T.H. Mubaraka and
70. J. Al-Zanqanawee, “Effect of Au and Ag nanoparticles addition on the morphological, structural and optical properties of ZnO thin films deposited by sol-gel method,” J. Ovonic Res., vol. 18, pp. 431-442, 2022.
71. Z. Ding, X. Hu, P.L. Yue, G.Q. Lu and
72. P.F. Greenfield, “Synthesis of anatase TiO2 supported on porous solids by chemical vapor deposition,” Catal. Today, vol. 68, p. 173, 2001.
73. G. Pecchi, P. Reyes, P. Sanhueza and J. Villasenor, “Photocatalytic degradation of pentachlorophenol on TiO2 sol-gel catalysts,” Chemosphere, vol. 43, p. 141, 2001.
74. Z.G. Hu, W.W. Li, J.D. Wu, J. Sun, Q.W. Shu,
75. X.X. Zhong, Z.Q. Zhu and J.H. Chu, “Optical properties of pulsed laser deposited rutile titanium dioxide films on quartz substrates determined by Raman scattering and transmittance spectra,” Appl. Phys. Lett., vol. 93, p. 181910, 2008.
76. A.E.D. Mahmoud, “Nanomaterials: green synthesis for water applications,” in O. Kharissova, L. Martínez and B. Kharisov (eds), Handbook of Nanomaterials and Nanocomposites for Energy and Environmental Applications, pp. 1-21, Springer, Cham, 2020.
77. M. Abushad, M. Arshad, S. Naseem, S. Husain and
78. W. Khan, “Role of Cr doping in tuning the optical and dielectric properties of TiO2 nanostructures,” Mater. Chem. Phys., vol. 256, p. 123641, 2020.
79. O.M. Abdulmunem, A.M. Jabbar, S.K. Muhammad, M.O. Dawood, S.S. Chiad and N.F. Habubi, “Investigation of Co-doped Cu2O thin films on the structural, optical and morphology by SPT,” J. Phys.: Conf. Ser., vol. 1660, p. 012048, 2020.
80. W. Zhu, Y. Xu, H. Li, B. Dai, H. Xu, C. Wang,
81. Y. Chao and H. Liu, “Photocatalytic oxidative desulfurization of dibenzothiophene catalyzed by amorphous TiO2 in ionic liquid,” Korean J. Chem. Eng., vol. 31, pp. 211-217, 2014.
82. M.L. Grilli, M. Yilmaz, S. Aydogan and B.B. Cirak, “Room temperature deposition of XRD-amorphous TiO2 thin films: investigation of device performance as a function of temperature,” Ceram. Int., vol. 44, pp. 11582-11590, 2018.
83. R. Renugadevi, T. Venkatachalam, R. Narayanasamy and S. Dinesh Kirupha, “Preparation of Co doped TiO2 nano thin films by sol-gel technique and photocatalytic studies of prepared films in tannery effluent,” Optik, vol. 127, pp. 10127-10134, 2016.
84. G. Sadanandam, K. Lalitha, V.D. Kumari,
85. M.V. Shankar and M. Subrahmanyam, “Cobalt doped TiO2: a stable and efficient photocatalyst for continuous hydrogen production from glycerol: water mixtures under solar light irradiation,” Int. J. Hydrogen Energy, vol. 38, pp. 9655-9664, 2013.
86. N. Méndez-Lozano, M. Apátiga-Castro,
87. A. Manzano-Ramírez, E.M. Rivera-Muñoz, R. Velázquez-Castillo, C. Alberto-González and M. Zamora-Antuñano, “Morphological study of TiO2 thin films doped with cobalt by metal organic chemical vapor deposition,” Results Phys., vol. 16, p. 102891, 2020, [Online]. Available: https://doi.org/10.1016/j.rinp.2019.102891.
88. B. Gong, X. Luo, N. Bao, J. Ding, S. Li and J. Yi, “XPS study of cobalt doped TiO2 films prepared by pulsed laser deposition,” Surf. Interface Anal., vol. 46, pp. 1043-1046, 2014.
89. A. Chanda, K. Rout, M. Vasundhara, S.R. Joshi and
90. J. Singh, “Structural and magnetic study of undoped and cobalt doped TiO2 nanoparticles,” RSC Adv., vol. 8, pp. 10939-10947, 2018.