Proceedings of International Conference on Applied Innovation in IT
2025/06/27, Volume 13, Issue 2, pp.585-593
Thiadiazole Derivative Impregnated on Cross-Linked Hydrogel for Water Retention and Adsorption of Nickel Ions for Sustainable Environment
Anwar Mohsen Sagban and Ayad Sulaiman Hamad Abstract: In this study, free radical copolymerization was used to prepare a hydrogel of poly (acrylic acid-co-2-amine -5-(3,5-dinitrophenyl)-1,3,4-thiadiazol) (poly-AA-ANT). The poly-AA-ANT hydrogel was characterized using Fourier transform infrared spectroscopy FTIR, Thermogravimetric analysis (TGA), and scanning electron microscopy (SEM), X-ry diffraction. The swelling of poly-AA-ANT was performed by using two solvents (water and methanol) each alone and found that the swelling ability in methanol was higher than for water. The removal of Ni2+ was conducted by immersing the poly-AA-ANT in a solution of Ni2+ and after a periol of time the residual we measured by atomic absorption spectrophotometer. The percentage of removal was 93.8%. The poly-AA-ANT hydrogel had a high swelling ratio of 546%. penetration rate of the poly-AA-ANT hydrogel coupled with the high swelling rate exposed to the internal adsorption sites. The high-water holding capacity of Poly-AA-ANT improved the moisture holding limit of soil for irrigation up to 24 days. systems as a result, Poly-AA-ANT has become an important addition to irrigation systems.
Keywords: Acrylic Acid, Azobisisobutyronitrile, Hydrogel, MBA, Adsorption.
DOI: 10.25673/120546
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References:
- M. Cempel and G. J. Nikel, "Nickel: a review of its sources and environmental toxicology," Polish Journal of Environmental Studies, vol. 15, no. 3, 2006.
- V. Bencko, "Nickel: a review of its occupational and environmental toxicology," Journal of Hygiene, Epidemiology, Microbiology, and Immunology, vol. 27, no. 2, pp. 237-247, 1983.
- L. J. Casarett, Casarett and Doull's Toxicology: The Basic Science of Poisons, New York: McGraw-Hill, 2008.
- P. P. M. Muniyan, "Effect of nickel on certain biochemical parameters in selected tissues of Cirrhinus mrigala."
- E. O. Uthus and R. A. Poellot, "Dietary folate affects the response of rats to nickel deprivation," Biological Trace Element Research, vol. 52, pp. 23-35, 1996.
- J. J. Scott-Fordsmand, "Toxicity of nickel to soil organisms in Denmark," Reviews of Environmental Contamination and Toxicology: Continuation of Residue Reviews, pp. 1-34, 1997.
- L. Anah and N. Astrini, "Isotherm adsorption studies of Ni (II) ion removal from aqueous solutions by modified carboxymethyl cellulose hydrogel," in IOP Conference Series: Earth and Environmental Science, vol. 160, p. 012017, IOP Publishing, 2018.
- A. Ewecharoen, P. Thiravetyan, E. Wendel, and H. Bertagnolli, "Nickel adsorption by sodium polyacrylate-grafted activated carbon," Journal of Hazardous Materials, vol. 171, no. 1-3, pp. 335-339, 2009.
- C. K. Ahn, Y. M. Kim, S. H. Woo, and J. M. Park, "Removal of cadmium using acid-treated activated carbon in the presence of nonionic and/or anionic surfactants," Hydrometallurgy, vol. 99, no. 3-4, pp. 209-213, 2009.
- F. Boudrahem, A. Soualah, and F. Aissani-Benissad, "Pb (II) and Cd (II) removal from aqueous solutions using activated carbon developed from coffee residue activated with phosphoric acid and zinc chloride," Journal of Chemical & Engineering Data, vol. 56, no. 5, pp. 1946-1955, 2011.
- W. Q. Fu, Y. Wen, W. J. Tang, and Z. Y. Yao, "Cu (II) removal from aqueous solution by ultrafiltration assisted with chestnut shell pigment," Water Conservation Science and Engineering, vol. 7, no. 4, pp. 419-428, 2022.
- Z. Chen, W. Wei, H. Chen, and B. J. Ni, "Recent advances in waste-derived functional materials for wastewater remediation," Eco-Environment & Health, vol. 1, no. 2, pp. 86-104, 2022.
- M. Simić, J. Petrović, T. Šoštarić, M. Ercegović, J. Milojković, Z. Lopičić, and M. Kojić, "A mechanism assessment and differences of cadmium adsorption on raw and alkali-modified agricultural waste," Processes, vol. 10, no. 10, p. 1957, 2022.
- M. Petrović, T. Šoštarić, M. Stojanović, J. Petrović, M. Mihajlović, A. Ćosović, and S. Stanković, "Mechanism of adsorption of Cu²⁺ and Zn²⁺ on the corn silk (Zea mays L.)," Ecological Engineering, vol. 99, pp. 83-90, 2017.
- Z. Chen, W. Wei, W. Zou, J. Li, R. Zheng, W. Wei, and H. Chen, "Integrating electrodeposition with electrolysis for closed-loop resource utilization of battery industrial wastewater," Green Chemistry, vol. 24, no. 8, pp. 3208-3217, 2022.
- S. Bolisetty, M. Peydayesh, and R. Mezzenga, "Sustainable technologies for water purification from heavy metals: review and analysis," Chemical Society Reviews, vol. 48, no. 2, pp. 463-487, 2019.
- Y. Wang, W. Wang, X. Shi, and A. Wang, "A superabsorbent nanocomposite based on sodium alginate and illite/smectite mixed-layer clay," Journal of Applied Polymer Science, vol. 130, no. 1, pp. 161-167, 2013.
- A. Pourjavadi, A. M. Harzandi, and H. Hosseinzadeh, "Modified carrageenan 3. Synthesis of a novel polysaccharide-based superabsorbent hydrogel via graft copolymerization of acrylic acid onto kappa-carrageenan in air," European Polymer Journal, vol. 40, no. 7, pp. 1363-1370, 2004.
- T. Wan, R. Huang, Q. Zhao, L. Xiong, L. Qin, X. Tan, and G. Cai, "Synthesis of wheat straw composite superabsorbent," Journal of Applied Polymer Science, vol. 130, no. 5, pp. 3404-3410, 2013.
- S. Pandey and S. Tiwari, "Facile approach to synthesize chitosan based composite—characterization and cadmium (II) ion adsorption studies," Carbohydrate Polymers, vol. 134, pp. 646-656, 2015.
- K. S. Kasprzak, F. W. Sunderman Jr, and K. Salnikow, "Nickel carcinogenesis," Mutation Research/Fundamental and Molecular Mechanisms of Mutagenesis, vol. 533, no. 1-2, pp. 67-97, 2003.
- H. Dumrul, A. N. Kursunlu, O. Kocyigit, E. Guler, and S. Ertul, "Adsorptive removal of Cu (II) and Ni (II) ions from aqueous media by chemical immobilization of three different aldehydes," Desalination, vol. 271, no. 1-3, pp. 92-99, 2011.
- V. K. Gupta, A. Rastogi, and A. Nayak, "Biosorption of nickel onto treated alga (Oedogonium hatei): application of isotherm and kinetic models," Journal of Colloid and Interface Science, vol. 342, no. 2, pp. 533-539, 2010.
- M. Sadeghi, "Synthesis of a biocopolymer carrageenan-g-poly(AAm-co-IA)/montmorilonite superabsorbent hydrogel composite," Brazilian Journal of Chemical Engineering, vol. 29, pp. 295-305, 2012.
- A. Ashri, N. Amalina, A. Kamil, S. Fazry, M. F. Sairi, M. F. Nazar, and A. M. Lazim, "Modified Dioscorea hispida starch-based hydrogels and their in vitro cytotoxicity study on small intestine cell line (FHS-74 Int)," International Journal of Biological Macromolecules, vol. 107, pp. 2412-2421, 2017.
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